By Yirmiyahu Yovel (edit.)
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Table 18b. Atomic [74 M IO]. 883(3) 0 0 0 0 0 Er(1) Er(2) Er (3) Ni 3b 6c 18f 18f 0 0 - Table 18d. Atomic positions in YsNi, - P4,2,2 space group [77 L 11. Y(2) Y(3) Co(l) co (2) Table 18~. Atomic sites in DysNi, C2/m space group [75 M 91. 7 R-3d: R,M, 48 [Ref. p. 405 Ni, oy 0 a Ni ‘/L < x c 3/L b 3/bc x < 5/k Fig. 44. Linkage of trigonal prisms in Y,Ni, in projection down a. Large circles represent Y atoms, small circles in the centers of the prisms, the Ni atoms. The inscribed numbers correspond to the x parameters multiplied by 100.
Magnetic properties of R&o compounds. 2 K in fields of 60 kOe. 2 K in pulsed fields of 160kOe. 2 K in fields of 30 kOe. Temperature of the peak in initial susceptibility. Determined in pulsed magnetic field. 2K. 5 . 05 9 63 52 2 0 ‘? 7 IO Table 5b. Magnetic properties of R,Ni compounds. 2 K in fields of 60 kOe. 2K in fields of 70 kOe. 2 K in pulsed field of 160kOe. Temperature of the peak in initial susceptibility. d. 1 R-3d: R,M 2 [Ref. p. 405 2 PB R&o /' /c- R = Nd R = Nd R3Ni PB /' 1 Ed 1 0 0 40 80 120 kOe 160 0 H- &O 80 120 kOe 160 H- Fig.
Coordination polyhedra in projection along the c axis of Er,Ni, structure. (a),(b) and (c) show, respectively, the Er(l)-, Er(2)- and Er(3)ccntrcd coordination polyhedra. (d) Trigonal prism of Er atoms surrounding one Ni atom (x) with three outer atoms: 2Er+ Ni [74 M lo]. Fig. 42. Stacking of polyhedra along the c axis in one hexagonal ccl1 of Er,Ni,. Successively, one regular octahedron of Er atoms ccntred at the origin (z=O), the CN16 polyhedron centred at Er(2)as described in Fig. 41(b), and the CN14 polyhedron centred at Er(1) at z=1/2 as described in Fig.